Dinuclear dialkoxo-bridged cyclopentadienylsiloxo titanium complexes
نویسندگان
چکیده
منابع مشابه
Dinuclear dialkoxo-bridged cyclopentadienylsiloxo titanium complexes.
The dinuclear dialkoxo-bridged complexes [(TiCl)(2)(mu-O(2)L)(mu-{(eta(5)-C(5)Me(4)SiMeO)(2)(mu-O)})] (O(2)L = 1,2-O(2)C(2)H(4), 1,2-O(2)C(6)H(4), 1,2-(OCH(2))(2)C(6)H(4), O(2)SiPh(2)) were obtained by reaction of [(TiCl(2))(2)(mu-{(eta(5)-C(5)Me(4)SiMeO)(2)(mu-O)})] () with the corresponding dilithium salt () or diol (, , ). Alkylation of and with ClRMg afforded [(TiR)(2)(mu-O(2)L)(mu-{(eta(5)...
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ژورنال
عنوان ژورنال: Dalton Transactions
سال: 2009
ISSN: 1477-9226,1477-9234
DOI: 10.1039/b820092k